IMMEDIATE
RESEARCH INTERESTS:
Inorganic Chemistry: a) The synthesis,
structural characterization and reactivity of transition metal complexes
containing sulfur-based ligands; b) the modeling of both industrial and
biological catalytic systems; and c) synthesis and structural characterization
of transition metal complexes with thiophenic ligands.
SELECTED PUBLICATIONS:
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Structure of (Dimethyldithiocarbamate)(triphenylphosphine)(h5-cyclopentadiene)
Ruthenium(II). A. W. Cordes and M. Draganjac, Acta Cryst., Sect. C., C44,
(1988), 363-364.
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Synthesis of [Ru(CO)2(Se4)2]2-.
An Anionic Ru2+ Polychalcogenide Complex. M. Draganjac, Sandeep
Dhingra, Song-Ping Huang and Mercouri Kanatzidis. Inorganic Chem., 29,
(1990), 590-591.
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New Organometallic Dithiooxalate
Compound. Synthesis and Structure of [Cp2ZrCl]2(dto).
Colin A. Hester, M. Draganjac and A. W. Cordes. Inorg. Chim. Acta, 184,
(1991), 137-139.
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Molecular structures of
[CpRu(PPh3)(dtoxa-H2O)]BF4 and {[CpRu(PPh3)2]2(µ-dtoxa)]}(BF4)2,
dtoxa = dithiooxamide. M. Draganjac, David Minick and A. W. Cordes. J.
Cryst. Spec. Res., 23, (1993), 265-271.
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The Reaction of CpRu(PPh3)2+
with Organic Thiols. Synthesis and Characterization of [CpRu(PPh3)2(RSH)]BF4,
R = benzyl, phenethyl, and the Molecular and Crystal Structure of [CpRu(PPh3)2(C6H5CH2CH2SH)]BF4.CH2Cl2.
Haengsoon Park, David Minick, M. Draganjac, A. W. Cordes, R. L. Hallford
and Gordon Eggleton. Inorg. Chim. Acta, 204, (1993), 195-198.
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Crystal and molecular
structure of [CpRu(PPh3)2(t-C4H9SH)]BF4.
David Minick, M. Draganjac, Joey W. Crump and A. W. Cordes. J. Cryst. Spec.
Res., 23, (1993), 629-632.
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The S-H Stretching Frequencies
in Ruthenium Mercaptan Complexes and the Crystal and Molecular Structures
of [CpRu(PPh3)2(s-C4H9SH)]BF4.CH2Cl2
and [CpRu(PPh3)2(i-C4H9SH)]BF4.CH2Cl2.
Haengsoon Park, David Minick, M. Draganjac, Joey W. Crump, A. W. Cordes
and Elizabeth M. Holt. Proc. Ark. Acad. Sci., 47, (1993), 142-144.
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The Reaction of CpRu(PPh3)2+
with Trimethylenesulfide. Synthesis and Molecular and Crystal Structure
of [CpRu(PPh3)2(SC3H6)]CF3SO3.
Haengsoon Park, M. Draganjac, S. R. Scott, A. W. Cordes and Gordon Eggleton.
Inorg. Chim. Acta, 221, (1994), 157-160.
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Structure of Cyclopentadienylbis(triphenylphosphine)(thioacetamide)ruthenium(II)
tetrafluoroborate. C. D. Bryan, A. W. Cordes and M. Draganjac. Acta Cryst.,
Sect. C, 50, (1994), 1231-1233.
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Molecular structure of
[CpRu(PPh3)2(C6H11SH)]BF4.CH2Cl2.
Yanjing Jiang, M. Draganjac and A. W. Cordes. J. Cryst. Chem., 25,
(1995), 653-656.
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Structural Assignments
in [CpRu(PPh3)2(n-PrSH)]BF4 by NMR Techniques.
Mark Draganjac and Robert Zey. NMR Exercises for the Undergraduate Laboratory/Classroom,
(Central Missouri State University Press, Warrensburg, MO:1995).
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Crystal and molecular
structure of Cp2Mo(mto), mto = monothiooxalate. Tanya Hagler,
M. Draganjac and Clifton Woods. J. Cryst. Chem., 25, (1995) 871-874.
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Molecular structure of
[CpRu(PPh3)2(tht)]BF4, tht = tetrahydrothiophene.
Yanjing Jiang, M. Draganjac and A. W. Cordes. J. Cryst. Chem., 26,
(1996) 657-660.
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Synthesis and molecular
structure of [CpRu(1,4,7-S3C6H12)]O3SCF3.
M. Green, M. Draganjac, Y. Jiang and A. W. Cordes. J. Cryst. Chem., 29,
(1999) 273-276.
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Synthesis and Molecular
Structure of [CpRu(PPh3)(pms)2]OTfl.3/4C2H4Cl2.
P. M. Nave, M. Draganjac, A. W. Cordes and T. M. Barclay. J. Ark. Acad.
Sci., 53, (1999), 147-149.
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Synthesis, molecular structure
and computational study of a ruthenium bis(thietane) complex. Paul
M. Nave, M. Draganjac, B. Ward, A.W. Cordes, T.M. Barclay, T. R. Cundari,
J. J. Carbó, F. Maseras. Inorg. Chim. Acta, 316, (2001), 13-18.
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Synthesis and Characterization
of a Ruthenium-Thioxane Complex. Amanda Wroble, Scotty Sproles, M.
Draganjac and Paul M. Nave. J. Ar. Acad. Sci., 55, (2001), 193-195.
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Synthesis of a Ruthenium-tetra(tht(dichloride
Compound and the Molecular Structure of the Partially Oxidized Compound
RuCl2(tht)2.2(tht-O)1.8. L. A. Thornton,
Jr., M. Draganjac, Andres Meza and A. W. Cordes. J. Ar. Acad. Sci., 55,
(2001), 189-190.
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Reaction of CpRu(PPh3)2Cl
with Six-member cyclothioethers. Structures of the [CpRu(PPh3)xL]X
Complexes (L = pentamethylene sulfide, x = 2, X = BF4-; L = 1,3-dithiane,
1,3,5-trithiane, x = 2, X = CF3SO3-; L = 1,4-dithiane, x = 1, X = BF4-
). Mark Green, M. Draganjac, Yanjing Jiang, Paul M. Nave, A. W. Cordes,
C. D. Bryan, J. K. Dixon, S. L. Folkert and C.-H. Yu, J. Chem. Cryst.,
33, (2003) 473-479.
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The Quest for Chain‑Link
Hydrogen Bonded Capsules: Self‑Assembly of C‑Methyl Calix[4]resorcinarene with
1,2‑bis(5’‑pyrimidyl) ethyne. Ivan Georgiev, Charles L. Barnes, Mark Draganjac
and Eric Bosch, Crystal Growth and Design, (2004), 4, 235‑239.
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