Arkansas State University
Department of Chemistry
and Physics
CHEM4204 Homework 3
Molecular Orbital Diagrams

 

a) Draw the M.O for CO2 using the following A.O. energies:

C 2s, - 157 kcm-1 ; 2p, - 86 kcm-1
O 2s, - 261 kcm-1; 2p, - 128 kcm-1

b) label the HOMO and LUMO

c) determine the B.O.

d) describe the magnetic properties

e) draw the diagram for Case I and explain why Case I doesn't work for CO2

Due Wednesday, February 6, 2008